The effect of molecular association upon gel-permeation chromatographic separations is examined. Application of a previously established GPC elution-volume/molar-volume relationship to the study of solvent/solute interactions is discussed. The use of such interactions to improve fractionating ability of GPC columns is described. Application of the GPC technique to fundamental studies of forces involved in intermolecular association is suggested.
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Cazes et al. (1969) studied this question.
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