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Synthetic saponites were suspended in aqueous solutions of poly(ethylene glycol) monomethyl and monooctyl ethers and studied by NMR techniques. Analysis of water deuteron quadrupolar splittings, 23 Na NMR relaxation rates of counterions, 13 C NMR relaxation rates, and 1 H NMR self-diffusion coefficients of oligomers provides a convergent picture on the oligomer interaction with saponites. Both isolated molecules and micelles mainly interact with the lower charged saponites.
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J. Grandjean (1998) studied this question.
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