Discrete complex ions with distorted cubane structure and tetrahedrally coordinated Mn centers are found in the first thiolato-substituted heterocubane complex 1a (shown on the right without iPr groups) and the analogous selenato complex 1b. Complexes 1 are also the first cubane clusters with mixed chalcogen ligand spheres containing exclusively divalent metal centers.
No takes yet. Share an insight, caveat, or question.
Stephan et al. (1994) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: