By the reduction of iron and removal of sulfur, the previously inaccessible [Fe8S6]4+ clusters (as cluster anion [Fe8S6I8]4− (1)) were synthesized from [Fe4S4]2+. This type of cluster, which contains exclusively FeII centers, is not only of interest as a molecular model for reactions of FeS, but may also undergo further reaction on account of the lack of ligands and the oxidation state of the metal.
No takes yet. Share an insight, caveat, or question.
Pohl et al. (1993) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: