All articles of this category Chiral thioarylimidazolines 1,2 were prepared as a new class of SN-hybrid ligands. Asymmetric allylic substitution of 1,3-diphenyl-2-propenyl pivalate 11 with dimethyl malonate in the presence of BSA-LiOAc has been successfully carried out with a chiral catalyst of a thioimidazoline 1 -palladium complex in high enantioselectivities of up to 96% ee. chiral imidazoline - thioimidazoline - palladium catalyst - asymmetric allylation - catalytic asymmetric allylation
No takes yet. Share an insight, caveat, or question.
Morimoto et al. (1997) studied this question.
Synapse has enriched 5 related papers. Consider them for comparative context: