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Palladium complexes of a variety of β- and γ-iminophosphines have been prepared and characterized by X-ray diffraction studies. Their properties as catalyst for three different Stille coupling reactions have been investigated and compared to catalytic performances of a phosphorus-containing dendrimer incorporating analogous γ-iminophosphine palladium complexes on the surface.
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Koprowski et al. (2002) studied this question.
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