The photopolymerization of vinyl monomers was studied by the system of metal‐amine complex and carbon tetrachloride. Addition of amines to the initiating system generally accelerates the polymerization. The acceleration by various sorts of amines in different solvents was examined. It was confirmed that the photopolymerization in question is of free radical character. The polymerization mechanism was discussed.
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Okimoto et al. (1974) studied this question.
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