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All articles of this category The construction of the fragments C 1 -C 9 3 and C 17 -C 27 , 4a of the bryostatins in a enantioselective and highly diastereoselective fashion is described. The usefulness of the "chiron" approach is illustrated with the synthesis of these fragments from, respectively, D-pantolactone ( 6 ) and D-isobutyl lactate ( 23 ) as chiral templates.
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Brabander et al. (1994) studied this question.
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