The controlled cleavage of coordination polymers consisting of well-defined large units can be employed for the rational synthesis of high nuclearity clusters. This synthetic concept is demonstrated by the conversion (schematically shown) of a three-dimensional ZnII coordination polymer containing repeating hexameric units with a “twin-anchor” arrangement of the metal ions into the corresponding hexanuclear cluster by reaction with a donor solvent.
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Lalioti et al. (2001) studied this question.
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