⌘+K

Pulse Explore Communities Researchers Journals

Browser extensionInstagram

Home Communities Explore

January 1, 1974Journal of the Chemical Society Perkin Transactions 2

Stable carbonium ions. Part VI. Inter-cation exchange rearrangements of ferrocenylalkylium ions

T. Derrick Turbitt W. E. Watts

View at Publisher

Ask AI

Bookmark

Share

Ask about this paper

Answers are grounded in this paper and cite their sources.

Ask your own question…

Abstract

In CF3CO2H solution, α-substituted 1-ferrocenylethylium and 1-ferrocenyl-1-methylethylium cations rearrange to a mixture of the isomeric β- and 1′-substituted cations in the presence of ferrocene or an alkylferrocene, by means of an equilibrium controlled transfer of the (MeCH) or (Me2C+) group between cations, ferrocene, or an alkyl derivative functioning as transport agent. Ruthenocenylalkylium ions, and thermodynamically more stable ferrocenylalkylium ions (e.g. FcCHPh, Fc2CH) do not undergo similar rearrangements.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

TURBITT et al. (1974) studied this question.

synapsesocial.com/papers/6a96214ddc0959f3a316515a https://doi.org/10.1039/p29740000189

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 10 related papers. Consider them for comparative context:

1Stereoelectronic substituent effects on intramolecular H-bonding in crowded o-anisic acidsJournal of the Chemical Society Perkin Transactions 2 · 2002
25-Diisopropoxyphosphoryl-5-methyl-1-pyrroline N-oxide, DIPPMPO, a crystalline analog of the nitrone DEPMPO: synthesis and spin trapping propertiesElectronic supplementary information (ESI) available: Tables of crystallographic data. See http://www.rsc.org/suppdata/p2/b2/b206909c/Journal of the Chemical Society Perkin Transactions 2 · 2002
34,4-p-Biphenyl bis-phosphinidene: generation of a bis-W(CO)5 complex and ab initio calculation of its electronic structureJournal of the Chemical Society Perkin Transactions 2 · 2002
4Calculation of Abraham descriptors from experimental data from seven HPLC systems; evaluation of five different methods of calculationElectronic supplementary information (ESI) available: Tables S1 to S5. See http://www.rsc.org/suppdata/p2/b2/b206927j/Journal of the Chemical Society Perkin Transactions 2 · 2002
5Solution phase, solid state and computational structural studies of the 2-aryl-3-bromoquinolin-4(1H)-one derivatives1Journal of the Chemical Society Perkin Transactions 2 · 2002
6EPR detection of the unstable tert-butylperoxyl radical adduct of the spin trap 5,5-dimethyl-1-pyrroline N-oxide: a combined spin-trapping and continuous-flow investigationJournal of the Chemical Society Perkin Transactions 2 · 2002
7Steric and electronic effects on the mechanism of nucleophilic substitution (SNAr) reactions of some phenyl 2,4,6-trinitrophenyl ethers with aniline and N-methylaniline in acetonitrile and in dimethyl sulfoxideJournal of the Chemical Society Perkin Transactions 2 · 2002
81,3-Dipolar additions involving allenes: A density functional study of concerted and stepwise mechanismsElectronic supplementary information (ESI) available: Cartesian co-ordinates of all the structures with their computed total energies. See http://www.rsc.org/suppdata/p2/b2/b206470gJournal of the Chemical Society Perkin Transactions 2 · 2002
9Hydrogen abstraction from ethylbenzene by imide-N-oxyl radicals with and without O2: a DFT theoretical studyJournal of the Chemical Society Perkin Transactions 2 · 2002
10N-Nitrosamide-mediated Ritter-type reactions.Journal of the Chemical Society Perkin Transactions 2 · 2002

More from Journal of the Chemical Society Perkin Transactions 2