The evolution of polymers incorporating the closo-carboranes C 2 B 5 H 7 and C 2 B 10 H 12 is reviewed. Both addition and condensation polymers and Copolymers are described which include various examples ofpolyesters, polyvinyls and polyamides. Primary emphasis is placed upon the polycarboranesiloxane polymers which exhibit unparalleled thermal stability.
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R. E. Williams (1972) studied this question.
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