A highly efficient non‐chiral‐pool synthesis of (+)‐1‐deoxynojirimycin has been realized (24 % overall yield, 11 steps, complete stereocontrol). A novel one‐pot enol ether metathesis/hydroboration/oxidation sequence is used for the selective formation of the all‐ trans cyclic triol. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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Danoun et al. (2009) studied this question.
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