TALIF measurements of oxygen atom density in the afterglow of a capillary nanosecond discharge

The atomic oxygen density has been measured in the afterglow of a capillary nanosecond discharge in 24–30 mbar synthetic air (N 2 : O 2 = 4 : 1) by the two-photon absorption laser-induced fluorescence (TALIF) technique, combined with absolute calibration by comparison with xenon TALIF. The discharge was initiated by a train of 30 ns FWHM pulses of alternating positive–negative–positive polarity, separated by 250 ns, with a train repetition frequency of 10 Hz. The amplitude of the first pulse was 10 kV in the cable. A flow of synthetic air through the tube provided complete gas renewal between pulse trains. The O-atom density measurements were made over the time interval 200 ns–2 µ s after the initial pulse. The gas temperature was determined by analysis of the molecular nitrogen second positive system optical emission spectrum. The influence of the gas temperature on the atom density measurements, and the reactions producing O atoms, are discussed.