An automated static total pressure measurement apparatus was used to measure isothermal vapor−liquid equilibria for five binary systems: trans -2-butene + methanol, + ethanol, + 2-propanol, + 2-butanol, and + 2-methyl-2-propanol at 332.3 K. Error analysis of the measured results has been presented. All systems exhibited positive deviation from Raoult's law. The trans -2-butene + methanol and trans -2-butene + ethanol systems showed azeotropic behavior.
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Zaytseva et al. (2004) studied this question.
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