Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO)2]2 caused unprecedented formation of tetranuclear rhodium complex Rh4(NCP)2(CO)4 having a gable-porphyrin-type structure, where two porphyrin pi systems were electronically connected by the rhodium cluster.
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Toganoh et al. (2006) studied this question.
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