Answers are grounded in this paper and cite their sources.
The anion coordination environments around Zr 4+ in ZrF 4 -BaF 2 -BaCl 2 -EuF 3 system glasses were examined by Zr K-EXAFS, Raman scattering, and IR absorption spectroscopies. Experiments were performed with 58ZrF 4 .(39-x)BaF 2 .xBaCl 2 .3EuF 3 glasses in which the x values were changed from zero to 29 in batch composition. These spectroscopic analyses reveal that the anion coordination environments around Zr 4+ are hardly changed by the successive substitution of Cl for F. These results agree with our previous study using molecular dynamics simulations.
No takes yet. Share an insight, caveat, or question.
Takahashi et al. (1995) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: