Thermally stable, high-quality ultrathin (EOT=13 A) CVD HfAlO gate dielectrics with poly-Si gate electrode have been investigated for the first time. Results demonstrate that while in situ doping with Al significantly increases the crystallization temperature of HfO/sub 2/ up to 900/spl deg/C and improves its thermal stability, it also introduces negative fixed oxide charges due to Al accumulation at the HfAlO-Si interface, resulting in mobility degradation. The effects of Al concentration on crystallization temperature, fixed oxide charge density, and mobility degradation in HfAlO have been characterized and correlated.
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Bae et al. (2003) studied this question.
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