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A microscopic theory of ionic transport in superionic conductors is presented. Based on a liquidlike description of the ionic carriers, it describes the frequency and temperature dependences of the conductivity. A sum rule is obtained and the theory predicts the existence of a conductivity peak which scales with the inverse of the ionic carrier mass. The results are in good agreement with recent data on Na and Ag β-aluminas.
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Huberman et al. (1974) studied this question.
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