A representation of the long-range dispersion series proposed by Smith and Thakkar (1972) and rediscovered by LeRoy (1974) requires a choice of n or equivalently chi =C 10 C 6 /(C 8 ) 2 . chi is nearly constant for interactions between pairs of S-state atoms. This constancy is explained in terms of the single oscillator model, the hydrogenic model and the Starkschall-Gordon model.
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Thakkar et al. (1974) studied this question.
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