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The palladium-catalyzed cross-coupling of intramolecularly stabilized divinyl- and diallylaluminium compounds 1 and 2 with haloarenes and chloroarene-Cr(CO)3 complexes has been studied. The coupling products were obtained in high yields (up to 98%) under relatively mild conditions (40-60 °C in THF, 3-12 h) in the presence of 5-10 mol% of PdCl2(PPh3)2.
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Schumann et al. (2003) studied this question.
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