Experimental analysis demonstrates dielectric changes during conformational shifts in thermochromic copper(II) compounds, indicating bistable electrical behavior for molecular switches.
The dielectric changes of thermochromic compounds, [Cu(dieten)2]X2 (X = BF4 and ClO4, dieten = N,N-diethylethylenediamine), have been induced by the transformation between square-planar and distorted-square-planar.
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Hayami et al. (2006) studied this question.
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