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The mass spectra of bicyclic phosphites of the type P(OCH2)3CR, where R = CH3, C2H5, and C3H7 and NO2, are reported, and their fragmentation patterns analyzed. Unlike trialkyl phosphites, these cyclic phosphites do not yield a large number of phosphorus‐containing fragment ions resulting from hydrogen rearrangement.
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David G. Hendricker (1967) studied this question.
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