Fractional frequency instability in the 10^−14 range with a thermal beam optical frequency reference

We demonstrate a means of increasing the signal-to-noise ratio in a Ramsey-Bordé interferometer with spatially separated oscillatory fields on a thermal atomic beam. The S01↔P13 intercombination line in neutral Ca40 is used as a frequency discriminator, with an extended cavity diode laser at 423 nm probing the ground state population after a Ramsey-Bordé sequence of 657 nm light-field interactions with the atoms. Evaluation of the instability of the Ca frequency reference is carried out by comparison with (i) a hydrogen-maser and (ii) a cryogenic sapphire oscillator. In the latter case the Ca reference exhibits a square-root Λ variance of 9.2×10−14 at 1 s and 2.0×10−14 at 64 s. This is an order-of-magnitude improvement for optical beam frequency references, to our knowledge. The shot noise of the readout fluorescence produces a limiting square-root Λ variance of 7×10−14/√τ, highlighting the potential for improvement. This work demonstrates the feasibility of a portable frequency reference in the optical domain with 10−14 range frequency instability.