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Three novel metal catalyzed cross‐coupling polymerization reactions which result in carbon‐carbon bond formation are described and discussed in context with other metal catalyzed cross‐coupling polymerization reactions. Diarylacetylene monomers and dimers are prepared by the phase transfer Pd(0)/Cu(I) catalyzed coupling of aryl halides with 2‐methyl‐3‐butyn‐2‐ol. Aryl‐alkyl bond forming polymerization reactions are achieved by the phase transfer Pd(0) catalyzed coupling of B‐alkyl‐9‐borabicyclo[3.3.1]nonane derivatives with aryl halides. Soluble polyphenylenes are prepared by the Ni(0) catalyzed homocoupling of substituted phenylenebistriflates in the presence of zinc.
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Percec et al. (1992) studied this question.
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