Exciton-exciton annihilation and exciton kinetics in poly(di-n-hexylsilane)

We have found that charge carriers can be generated by exciton-exciton annihilation in solid films of poly(di-n-hexylsilane). We use this phenomenon to study the kinetics of excitons at ambient temperature and show that the rate constant for exciton-exciton annihilation {γ} is 2×{}10^-7 cm³ s^-1, in excellent agreement with the value we obtained previously by other means. The quantum efficiency for carrier production, at an electric field of 2×{}10⁵ V cm^-1, is 1.3×{}10^-3 per annihilation event. We also show that {γ} is independent of the initial energy of the exciton state, even to energies far out on the long-wavelength tail of the exciton absorption band, and that the excitons remain mobile throughout their 600-ps lifetime.