An all-metal facility has been built to handle about 1000 Ci of tritium for studies of the tritium behavior in metals. First measurements of the pressure-composition-temperature relationship for the palladium-tritium system PdTₓ are reported for the pressure range 0.1≤p≤2 bar, the composition range 0.02≤x≤0.65, and the temperature range 35≤T≤125^∘C together with the results of the PdH and PdD systems measured under the same experimental conditions. The main conclusions are that the inequality p_T₂>p_D₂>p_H₂ holds at equal concentrations and temperatures and that the β→α transition enthalpies show a strong isotopic effect, whereas the entropies do not.
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Lässer et al. (1983) studied this question.
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