We have grown films on polycrystalline Si using excited ozone produced by ultraviolet light irradiation of ozone, and characterized their electrical properties in the metal-insulator-semiconductor capacitor configuration. films of thickness on poly-Si layers were grown in even at room temperature. The leakage current density across the film fitted well the Fowler-Nordheim tunnel current behavior and breakdown occurred at above , showing that the film was of device quality. The rate of Si oxidation by excited ozone was similar for both Si(100) and Si(111) wafers, as was the interface trap density . These results indicate that excited ozone can form a homogenous film on poly-silicon. We conclude that excited ozone is one of the most efficient reactive species for film formation on poly-Si at room temperature.
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Kameda et al. (2007) studied this question.
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