Free-ion and crystal-field energy parameters for trivalent lanthanide ions (Ln3+) in Cs2NaLnCl6 and Cs2NaYCl6 are presented and discussed. Spin-correlated crystal-field parameters are determined for those systems for which sufficient data are available. The superposition model is used to compare the crystal-field interactions in the Cs2NaYCl6:Ln3+ and LaCl3:Ln3+ systems.
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Reid et al. (1985) studied this question.
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