Self-cyclization of four HgCl2 units and four ditopic 1,3-bis(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene (bbimms) ligands has resulted in the assembly of the neutral nanotube [Hg4Cl8(bbimms)4] containing two compartments which can accomodate DMF and DMSO guest molecules (see picture). Crystal packing arranges all the tubes into an extended pipeline structure.
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Su et al. (2003) studied this question.
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