The nanoporous nickel phosphate VSB-5 has been synthesized without seeding by using inorganic bases instead of the reported template molecule, 1,3-diaminopropane. This synthesis demonstrates that large-pore metal phosphates may be synthesized without template molecules and the synthesis method can be very simple, inexpensive, and environmentally benign.
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Jhung et al. (2004) studied this question.
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