1,4‐Dipolar cycloaddition reactions of the pyrimidinium‐4‐olate of type 1 with phenyl isocyanate and isothiocyanates yielding 3 as well as the synthesis of the title compound 4 and its cycloaddition reactions with two electron‐rich CC‐multiple bond systems with formation of 5 and 6 are described.
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Gotthardt et al. (1987) studied this question.