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Metalloamination–alkylation of representative N,N-dimethylhydrazinoalkenes has been shown to be effectively catalyzed by CuBr·SMe2, CuCN, and CuI. The current method obviates the use of stoichiometric CuCN(LiCl)2 as a promoter for the electrophilic functionalization event.
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Mickelsen et al. (2017) studied this question.
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