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August 6, 2004Synlett

Indium(III) Acetate-Catalyzed 1,4-Reduction and Reductive Aldol Reactions of α-Enones with Phenylsilane

Katsukiyo Miura Akíra Hosomi Yusuke Yamada Mitsuru Tomita

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Abstract

A catalytic amount of In(OAc)3 smoothly promoted 1,4-reduction of certain α-enones with PhSiH3 in ethanol at ambient temperature. The intermediary enolates could be used for inter- and intramolecular aldol reactions and intramolecular Michael addition.

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Miura et al. (2004) studied this question.

synapsesocial.com/papers/6a985646cc61a2345e6c7a55 https://doi.org/10.1055/s-2004-830862

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