The first example of a [1]ferrocenophane with a heavier group 13 element in the bridging position is described. The [1]aluminaferrocenophane, with the aluminum atom equipped with a bulky and intramolecularly stabilizing ligand, has been synthesized and structurally characterized by NMR spectroscopy and single-crystal X-ray analysis.
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Schachner et al. (2005) studied this question.
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