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A highly nonplanar metallacyclic ring with a nucleophilic sulfur atom is contained in the binuclear complex 2, which is formed by reduction of the benzothiophene complex 1 in the presence of additional ligands (L = CO, P(OMe)3, P(OEt)3). This reaction, which proceeds by the insertion of manganese into the S-C(aryl) bond, is of interest in the context of catalytic desulfurization of fossil fuels.
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Dullaghan et al. (1996) studied this question.
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