Cement-Free Binders in Alumina-Magnesia Refractory Castables—A Review

To solve the problem of the accelerated deterioration of calcium aluminate (CAC)-bonded alumina-magnesia refractory castables during the secondary refining process, the development of cement-free binders has emerged as one significant research field of castables. The hydration behavior, curing mechanism, and properties of the most recent research on cement-free binders are compared in this paper. The problems and the modification of each binder of recent research are summarized. High-temperature performance of the castables bonded by traditional hydraulic cement-free binders (ρ-Al2O3 and activated MgO) is outstanding, explosive spalling resistance of the castables bonded by sol binders (silica sol, alumina sol) is good, and the properties of the castables bonded by novel organic hydratable binder (hydratable magnesium citrate) combine the advantages of these two binders above, but the mid-temperature mechanical strength is low. Furthermore, alumina-magnesia castables bonded by organic-composited inorganic cement-free binders are expected to be a future domain.