The disintegration of Rh clusters on an Al2O3 surface induced by CO, the elementary steps, and timescale of the reaction are analyzed for the first time by energy-dispersive X-ray absorption fine structure (DXAFS) at a time resolution of 100 ms (see picture). This study by the improved time-resolved DXAFS technique provides a new research area of structural dynamics of catalytically active materials at surfaces.
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Suzuki et al. (2003) studied this question.
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