Unique hollow heterostructured CdS/Cd0.5Zn0.5S-Mo1−xWxS2: Highly-improved visible-light-driven H2 generation via synergy of Cd0.5Zn0.5S protective shell and defect-rich Mo1−xWXS2 cocatalyst

Photocatalytic water splitting for hydrogen (H 2 ) production is a green sustainable technology, in which highly-efficient steady photocatalysts are fundamentally required. In this work, unique CdS/Cd 0.5 Zn 0.5 S-Mo - 1− x W x S 2 photocatalyst constructed by CdS hollow nano-spheres with successively surface-modified Cd 0.5 Zn 0.5 S shell and defect-rich Mo 1− x W x S 2 ultrathin nanosheets was reported for the first time. Interestingly, the Cd 0.5 Zn 0.5 S shell could greatly enhance the photo-stability and reduce the carrier recombination of CdS. Meanwhile, enriching active sites and accelerating charge transfer could be achieved via anchoring defect-rich Mo 1− x W x S 2 onto CdS/Cd 0.5 Zn 0.5 S hollow heterostructures. Specifically, the optimized CdS/Cd 0.5 Zn 0.5 S-Mo 1− x W x S 2 (6 h Cd 0.5 Zn 0.5 S-coating, 7 wt.% Mo 1− x W x S 2 , x = 0.5) hybrid delivered an exceptional H 2 generation rate of 215.99 mmol·g −1 ·h −1 , which is approximately 502, 134, and 23 times that of pure CdS, CdS/Cd 0.5 Zn 0.5 S, and 3 wt.% Pt-loaded CdSZCd 0.5 Zn 0.5 S, respectively. Remarkably, a high H 2 evolution reaction (HER) apparent quantum yield (AQY) of 64.81% was obtained under 420-nm irradiation. In addition, the CdS/Cd 0.5 Zn 0.5 S-Mo 1− x W x S 2 was also durable for H 2 production under long-term irradiation. This work provides valuable inspirations to rational design and synthesis of efficient and stable hybrid photocatalysts for solar energy conversion.