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The spontaneous and face‐specific copolymerization of [l.l.l]propellane and maleic anhydride to give the strictly alternating 1:1 copolymer 2 is described. The molecular weight of 2 after transformation into the corresponding diester 5c was determined to be 80.000 (Mn) and 220.000 (Mw), respectively.
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Gosau et al. (1990) studied this question.
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