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Sterically relaxed cation radical cage compounds with cis configurations are formed by the oxidation of the neutral compounds trans-l and trans-2. The central tetrathiafulvalene cores in cis-1′+ and cis-2′+ are planar and exhibit reversible redox chemistry. The trans–cis isomerization occurs faster in the case of the more constrained neutral cage trans-l.
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Boubekeur et al. (1994) studied this question.
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