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TiO 2 nanocrystallites are prepared by hydrolysis of titanium tetraisopropoxide in the presence of N, N ‘-2,6-pyridinediylbis[undecamide]. The latter stabilizes the resulting semiconductor sol and provides sites at the surface of a nanocrystallite for selective binding of a uracil derivative by complementary hydrogen bonding. Addition of 6-( N -tridecylundecamido)methyluracil results in self-assembly of a heterosupermolecule subsequently characterized by 1 H NMR and FT-IR spectroscopies.
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Cusack et al. (1997) studied this question.
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