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September 3, 2026MoleculesOpen Access

MXene/Carbon Nanotube/Poly(ethylene oxide) Heterostructured Interface for Polysulfide Regulation in Lithium–Sulfur Batteries

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Authors

BLBingjie LiuHarbin Medical UniversityLWLinin WangChina University of Petroleum, BeijingYKyangchuan keChina University of Petroleum, Beijing

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Implication

Experimental study demonstrates suppressed polysulfide shuttling and improved cycling in lithium–sulfur cells, suggesting an effective multifunctional separator strategy.

Key Points

  • Develop a multifunctional MXene/carbon nanotube/poly(ethylene oxide) heterostructured separator coating to mitigate polysulfide shuttling and accelerate sulfur redox kinetics in lithium–sulfur batteries.
  • Fabricated a composite separator interface combining polar MXene sheets, conductive carbon nanotubes, and poly(ethylene oxide).
  • Characterized charge-transfer resistance, potentiostatic Li2S deposition kinetics, and electrochemical performance during rate testing and long-term cycling.
  • The MX/CNT/PEO@PP separator reduced charge-transfer resistance from 175.9 Ω for pristine polypropylene to 15.7 Ω, representing a 91.1% reduction.
  • The cell achieved an initial discharge capacity of 1613 mAh g⁻¹ at 0.1 C, sustaining average capacities of 1331.1 mAh g⁻¹ at 0.1 C and 803.1 mAh g⁻¹ at 2 C.
  • Long-term cycling at 2 C demonstrated a retained capacity of 319.3 mAh g⁻¹ after 1000 cycles with an average decay rate of 0.064% per cycle.

Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/6a9935f3636c6408cfa7ea05https://doi.org/10.3390/molecules31173078
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