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We provide the first detailed time-resolved mechanistic information on the protonation of a model of the subsite of [FeFe]-hydrogenase, [Fe2(mu-pdt)(CO)4(PMe3)2]; the deceptively simple stoichiometric reaction is shown to be limited by the rate of protonation of the basal-apical isomer followed by its rearrangement to the transoid basal form.
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Wright et al. (2009) studied this question.
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