The densities of binary and ternary mixtures were measured for the system 1-ethyl-3-methylimidazolium bis(perfluoroethylsulfonyl)imide ([EMIM] + [BETI] − ) + methanol or + acetone and [EMIM] + [BETI] − + methanol + acetone, respectively, at T = (298.15, 303.15, and 313.15) K, and the speed of sound data for the binary system 1-ethyl-3-methylimidazolium diethyleneglycol monomethylethersulfate ([EMIM] + [CH 3 (OCH 2 CH 2 ) 2 OSO 3 ] − ) + methanol were measured at T = 298.15 K. The excess molar volumes were calculated from the experimental densities and were fitted to the Redlich-Kister equation for the binary system. The excess molar volumes, V m E, for the binary system ([EMIM] + [BETI] − + methanol) were positive for low mole fractions of methanol, and for the binary system ([EMIM] + [BETI] − + acetone), excess molar volumes were negative throughout the whole composition range. The ternary excess molar volumes were negative for all three temperatures. The isentropic compressibility for the binary system ([EMIM] + [CH 3 (OCH 2 CH 2 ) 2 OSO 3 ] − + methanol) was negative over the entire composition range. The results have been interpreted in terms of the intermolecular interactions between the ionic liquid and the organic solvents.
No takes yet. Share an insight, caveat, or question.
Deenadayalu et al. (2008) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: