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Manganese oxide nanoparticles with narrow size distribution were prepared in large scale by arc sublimation of bulk MnO . Although MnO is antiferromagnetic, the as-prepared manganese oxide nanoparticles exhibit ferromagnetic behaviors with coercivity and exchange bias up to 417,065 A/m and 162,099 A/m at 5 K, respectively. We attribute these anomalous magnetic properties to the presence of ferrimagnetic Mn 3 O 4, uncompensated surface spins and their coupling to the antiferromagnetic MnO .
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Z. et al. (2010) studied this question.
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