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A free phosphine/thioether/borane ligand ( 5 ) suitable to position a Lewis acidic borane in close proximity to a coordinated late transition metal has been prepared. Reaction with 0.5 [Pd 2 (dba) 3 ] gave a zwitterionic palladium(II) η 3 -boratoxypentadienyl complex with the empirical formula [Pd(dba)( 5 )].
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Emslie et al. (2006) studied this question.
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