Electrokinetc Study of Synthetic Smectites by Flat Plate Streaming Potential Technique

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ζ potentials of synthetic smectites with different locations of lattice charges, i.e., saponite and hectorite, were investigated as functions of pH and NaCl concentration by a flat plate streaming potential technique where two smectite-coated plates were separated by a Teflon gasket to form a slit channel. The lattice charge of saponite originates from the isomorphous substitution of Si 4+ by Al 3+ ions in tetrahedral silica sheets, whereas the lattice charge of hectorite is caused by the isomorphous substitution of Mg 2+ by Li + ions in octahedral magnesia sheets. The ζ potential for saponite was more sensitive to the pH of electrolyte solution than that for hectorite in acidic solution. Such a difference in pH dependence of the ζ potential could be explained by the difference in the location of the lattice charges between saponite and hectorite as a result of an analysis of the inner Helmholtz layer capacitance by using the Gouy−Chapman−Stern−Graham (GCSG) model with a single-site dissociation of surface groups. On the other hand, the dependence of the ζ potential on NaCl concentrations could not be fully interpreted by the GCSG model with a single value of the outer Helmholtz layer capacitance, which suggests a shift of the shear plane and/or a change in the dielectric constant of the outer Helmholtz layer with changing NaCl concentration.