Answers are grounded in this paper and cite their sources.
The effects of inert (non-hydrogen donor) cosolvents on transient complex formation between a nitroxide radical and two hydrogen donors are examined by EPR methods. For both C6H5OH and CF3CH2OH the complex association constants are lower and the radical-donor hyperfine coupling constants are higher in more polar cosolvents. The results are interpreted by using a model based on donor acidity and the role of the cosolvent in solvating each of the species in solution.
No takes yet. Share an insight, caveat, or question.
Al-Bala'a et al. (1991) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: