Quasi-One-Dimensional Spin Excitations in the Iron Pnictide NaFe 0.53 Cu 0.47 As

Spectroscopic measurements in model 1D correlated systems offer insights for understanding their two-dimensional counterparts, which include the cuprate and iron pnictide/chalcogenide superconductors. A major challenge is the identification of such correlated systems with dominantly 1D physics. In this Letter, inelastic neutron scattering measurements on NaFe0.53Cu0.47As single crystal directly reveal quasi-1D spin excitations, resulting from atomic order that leads to magnetic Fe and nonmagnetic Cu chains. The dominant exchange interaction is antiferromagnetic along the chain [SJ∥≈90.1(3) meV], whereas the inter-chain couplings are much weaker [SJ⊥≈-2.4(1) meV and SJc≈0.15(5) meV]. The quasi-1D spin excitations in NaFe0.53Cu0.47As stem from both the Néel and stripe vectors, with Néel excitations sensitive to Fe impurities on the Cu site. The spin excitations in quasi-1D NaFe0.53Cu0.47As and quasi-2D FeSe exhibit a striking resemblance, suggesting a common origin for their coexistent stripe and Néel excitations. Our findings demonstrate magnetic dilution in NaFeAs leads to dimension reduction of its magnetic degree of freedom, presenting a strategy for discovering low-dimensional quantum materials.