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A method for the synthesis of gaseous BrNO 2 at concentrations of the order of 10 -9 mol/cm 3 at atmospheric pressure is described, based on the heterogeneous reaction of ClNO 2 with aqueous bromide solutions. We measured the gas-phase infrared absorption cross sections in the range 700−1800 cm -1 . The matrix isolation spectrum was recorded for identification by comparison with literature data.
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Frenzel et al. (1996) studied this question.
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